QB Issue Resolution:

Open the Items List and attach from there. If you don’t see it, then right click, select Customize Columns, and add the ATTACH column here.

Resolution for Issue 'can a picture be assigned to a part ?' available: Yes (Solved).
Source: Intuit Community forum.

can a picture be assigned to a part ?: this issue or error code is a known issue in Quickbooks Online (QBO) and/or Quickbooks. Support for this issue is available either by self-service or paid support options. Experts are available to resolve your Quickbooks issue to ensure minimal downtime and continue running your business. First try to resolve the issue yourself by looking for a resolution described below. If it is a complex issue or you are unable to solve the issue, you may contact us by clicking here or by using other support options.

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